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Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhancedRaman spectroscopy substrate

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 15-23 doi: 10.1007/s11705-022-2177-8

摘要： Recently, various semiconductor/metal composites have been developed to fabricate surface-enhanced Raman spectroscopy substrates. However, low metal loading on semiconductors is still a challenge. In this study, cystine was introduced to increase the accumulation of gold nanoparticles on zinc oxide, owing to the biomineralization property of cystine. Morphological analysis revealed that the obtained ZnO/Au/cystine composite not only had a higher metal loading but also formed a porous structure, which is beneficial for Raman performance. Compared with ZnO/Au, the ZnO/Au/cystine substrate displayed a 40-fold enhancement in the Raman signal and a lower limit of detection (10–11 mol·L−1) in the detection of rhodamine 6G. Moreover, the substrate has favorable homogeneity and stability. Finally, ZnO/Au/cystine displayed excellent performance toward crystal violet and methylene blue in a test based on river water samples. This study provided a promising method to fabricate sensitive semiconductor/noble metal-based surface-enhanced Raman spectroscopy substrates for Raman detection.

关键词： biomineralization     cystine     semiconductor/metal composite     SERS detection     Raman detection    

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SERS nanoprobes for bio-application

Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong

《化学科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 428-441 doi: 10.1007/s11705-015-1536-0

摘要： The ability to tune the size, shape, composition and surface properties impart nanoparticles with the desired functions for bio-application. This article highlights some of the recent examples in the exploration of metal (e.g., gold and silver) nanoparticles, especially those with magnetic properties and bio-conjugated structures, as theranostic nanoprobes. Such nanoprobes exhibit tunable optical, spectroscopic, magnetic, and electrical properties for signal amplifications. Examples discussed in this article will focus on the nanoproble-enhanced colorimetric detection and surface enhanced Raman scattering (SERS) detection of biomarkers or biomolecules such as proteins and DNAs. The understanding of factors controlling the biomolecular interactions is essential for the design of SERS nanoprobes with theranostic functions.

关键词： surface-enhanced Raman scattering     functional nanoprobes     bio-conjugation     metal nanoparticles     magnetic properties     theranostic materials    

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V-shaped substrate for surface and volume enhanced Raman spectroscopic analysis of microplastics

《环境科学与工程前沿（英文）》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1578-8

摘要：

● V-shaped substrate was obtained for SERS analysis of microplastics (diameter ≈ 1 μm).

关键词： SERS     V-shaped     AAO     Microplastic     Atmospheric aerosol    

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超短脉冲激光制造及表面加工微米器件 Review

于泳超, 白石, 王树同, 胡安明

《工程（英文）》 2018年 第4卷 第6期   页码 779-786 doi: 10.1016/j.eng.2018.10.004

摘要：

超短脉冲激光在材料加工方面具有独特的优势。其对焦点之外区域的热影响效应非常有限，使超短脉冲激光可被应用于微米甚至纳米尺寸的精密加工。另外，非线性多光子效应使超短脉冲激光可以加工多种透明材料，包括玻璃以及透明高分子材料。基于这些特点，我们利用激光直写技术在高分子衬底上成功制造出了具有三维（3D）结构的高性能微型超级电容器（MSC），在0.1 mA·cm–2的电流密度下表现出42.6 mF·cm–2的峰值比电容。同时，也制造出了可用于探测多种“味道”的柔性传感器阵列。对传感器电极表面进行了不同的处理，如镀金、沉降氧化石墨烯（rGO）以及沉积聚苯胺（PANI）。通过对采集的数据进行主成分分析（PCA），这一传感器阵列可以成功地检测出样品内的不同物质。另外，在3D 结构玻璃微流体通道内由全飞秒激光加工出了具有2D周期性结构的纳米金属表面，可用于实时表面增强拉曼散射（SERS）的检测。全飞秒激光加工过程包括激光烧蚀、激光还原和激光诱导表面纳米工程。这些工作证明了超短脉冲激光在表面精密加工中的巨大潜力。

关键词： 超短脉冲激光加工     微米器件     超级电容器     电子舌     表面增强拉曼光谱    

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Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

《能源前沿（英文）》 2009年 第3卷 第1期   页码 60-79 doi: 10.1007/s11708-009-0011-3

摘要： Radiative properties of rough surfaces, particulate media and porous materials are important in thermal engineerit transfer between surfaces and volume elements in participating media, as well as for accurate radiometric temperature measurements. In this paper, recent research on scattering of thermal radiation by rough surfaces, fibrous insulation, soot, aerogel, biological materials, and polytetrafluoroethylene (PTFE) was reviewed. Both theoretical modeling and experimental investigation are discussed. Rigorous solutions and approximation methods for surface scattering and volume scattering are described. The approach of using measured surface roughness statistics in Monte Carlo simulations to predict radiative properties of rough surfaces is emphasized. The effects of various parameters on the radiative properties of particulate media and porous materials are summarized.

关键词： aerogel     fiber     particle scattering     radiative properties     soot     surface roughness    

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Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

《能源前沿（英文）》 2018年 第12卷 第1期   页码 43-71 doi: 10.1007/s11708-018-0524-8

摘要： Vibrational spectroscopy is one of the key instrumentations that provide non-invasive investigation of structural and chemical composition for both organic and inorganic materials. However, diffraction of light fundamentally limits the spatial resolution of far-field vibrational spectroscopy to roughly half the wavelength. In this article, we thoroughly review the integration of atomic force microscopy (AFM) with vibrational spectroscopy to enable the nanoscale characterization of emerging energy materials, which has not been possible with far-field optical techniques. The discussed methods utilize the AFM tip as a nanoscopic tool to extract spatially resolved electronic or molecular vibrational resonance spectra of a sample illuminated by a visible or infrared (IR) light source. The absorption of light by electrons or individual functional groups within molecules leads to changes in the sample’s thermal response, optical scattering, and atomic force interactions, all of which can be readily probed by an AFM tip. For example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermal expansion or temperature rise. Therefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermal response of a sample. Optical scattering methods based on scanning near-field optical microscopy (SNOM) correlate the spectrum of scattered near-field light with molecular vibrational modes. More recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the optical force gradient due to the light absorption by molecular vibrational resonances using AFM’s superb sensitivity in detecting tip-sample force interactions. Such recent efforts successfully breech the diffraction limit of light to provide nanoscale spatial resolution of vibrational spectroscopy, which will become a critical technique for characterizing novel energy materials.

关键词： vibrational spectroscopy     atomic force microscopy     photo-thermal induced resonance     scanning near-field optical microscopy     tip-enhanced Raman spectroscopy     photo-induced force microscopy     molecular resonances     surface phonon polaritons     energy materials    

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Enhanced photocatalytic water splitting with surface defective SrTiO

Junying LIU, Zhidong WEI, Wenfeng SHANGGUAN

《能源前沿（英文）》 2021年 第15卷 第1期   页码 700-709 doi: 10.1007/s11708-021-0735-2

摘要： Surface reconstructed SrTiO nanocrystals were synthesized by a thermal treatment process in presence of NaBH and SrTiO nanocrystals. The surface reconstruction of SrTiO nanocrystals is attributed to the introduction of surface oxygen vacancies or Ti sites (such as Ti and Ti ) during the hydrogenation treatment process. The light absorption and the charge transfer ability of SrTiO nanocrystals are simultaneously enhanced due to surface oxygen vacancies or Ti sites (such as Ti and Ti ), which are beneficial to photocatalytic water splitting. Meanwhile, these defects also change the redox potential of the photocatalysts. Since there existed a synergistic effect between the three, the ratio of hydrogen to oxygen production was also regulated.

关键词： SrTiO3     surface reconstruction     oxygen vacancies     photocatalytic water splitting    

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Chemical mapping of cement pastes by using confocal Raman spectroscopy

Fengjuan LIU,Zhihui SUN

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 168-173 doi: 10.1007/s11709-015-0323-9

摘要： In the present study, chemical mapping on the hydration process of cement paste with water-to-cement ( / ) ratio of 0.60 was implemented by Raman spectroscopy (RS). The RS was applied to study the paste from 12 hours after mixing to 28 days. Cement ingredients and hydration products, including calcium silicates (C S and C S), calcium hydroxide (CH), and ettringite, were quantitatively studied. From the research, it is observed that calcium silicates were consumed gradually with the increased hydration age. Calcium hydroxide increased and tended to cluster in the pore vicinity during hydration. Ettringite was found to form on the surface of the unreacted particles, which was shown as a mixed zone of ettringite and calcium silicates in the maps. It is concluded from the study that chemical mapping was an effective method to assist in visualizing particle dispersion and connection on top of the quantitative analysis.

关键词： chemical mapping     Raman spectroscopy     calcium silicates     calcium hydroxide     ettringite    

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Enhanced production of laccase by

Wei SUN, Meiying XU, Chunyu XIA, Anhua LI, Guoping SUN

《环境科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 200-210 doi: 10.1007/s11783-012-0457-0

摘要： The effect of physical parameters of cultivation (load volume, temperature, pH, agitation, inoculum size, and incubation period) in the production of laccase by wood-rotting basidiomycete were studied using diluted molasses distillery wastewater (MDW) as a major composition. Using fractional factorial design, our study first identified load volume, agitation, and inoculum size as statistically significant factors. Optimal preferences and mutual interactions of the factors were then determined by the response surface method, which is based on the center composite design. A quadratic model was used to fit the experimental data. The optimized operational parameters for laccase production were determined to be the following: culture temperature of 25°C, pH 4, load volume of 40 mL diluted MDW in 150 mL flask, agitation rate of 183 r·min , inoculation of 11.5% v/v, and cultivation time of 6 d. The experimental validation under these conditions (the maximum laccase production of 2198.2 U·mL was within the confidence interval) subsequently verified the accuracy of the constructed model. Moreover, the removal of chemical oxygen demand and nitrogen of MDW reached 62.85% and 48.00% respectively, and the decolorization ratio under the optimal condition was 41.85%. The enhanced production of laccase by is a new recovery strategy for MDW.

关键词： laccase     Coriolus hirsutus     fractional factorial design     response surface method     molasses distillery wastewater    

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Construction of nitrogen-doped carbon cladding LiMnO film electrode with enhanced stability for electrochemically

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 2050-2060 doi: 10.1007/s11705-023-2343-7

摘要： Reducing the dissolution of Mn from LiMn2O4 (LMO) and enhancing the stability of film electrodes are critical and challenging for Li+ ions selective extraction via electrochemically switched ion exchange technology. In this work, we prepared a nitrogen-doped carbon cladding LMO (C-N@LMO) by polymerization of polypyrrole and high-temperature annealing in the N2 gas to achieve the above purpose. The modified C-N@LMO film electrode exhibited lower Mn dissolution and better cyclic stability than the LMO film electrode. The dissolution ratio of Mn from the C-N@LMO film electrode decreased by 42% compared to the LMO film electrode after 10 cycles. The cladding layer not only acted as a protective layer but also functioned as a conductive shell, accelerating the migration rate of Li+ ions. The intercalation equilibrium time of the C-N@LMO film electrode reached within an hour during the extraction of Li+ ions, which was 33% less compared to the pure LMO film electrode. Meanwhile, the C-N@LMO film electrode retained evident selectivity toward Li+ ions, and the separation factor was 118.38 for Li+ toward Mg2+ in simulated brine. Therefore, the C-N@LMO film electrode would be a promising candidate for the recovery of Li+ ions from salt lakes.

关键词： LiMn2O4     lithium extraction     surface coating     cyclic stability     Mn dissolution    

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Effect of light scattering on the performance of a direct absorption solar collector

Kwang Hyun WON, Bong Jae LEE

《能源前沿（英文）》 2018年 第12卷 第1期   页码 169-177 doi: 10.1007/s11708-018-0527-5

摘要： Recently, a solar thermal collector often employs nanoparticle suspension to absorb the solar radiation directly by a working fluid as well as to enhance its thermal performance. The collector efficiency of a direct absorption solar collector (DASC) is very sensitive to optical properties of the working fluid, such as absorption and scattering coefficients. Most of the existing studies have neglected particle scattering by assuming that the size of nanoparticle suspension is much smaller than the wavelength of solar radiation (i.e., Rayleigh scattering is applicable). If the nanoparticle suspension is made of metal, however, the scattering cross-section of metallic nanoparticles could be comparable to their absorption cross-section depending on the particle size, especially when the localized surface plasmon (LSP) is excited. Therefore, for the DASC utilizing a plasmonic nanofluid supporting the LSP, light scattering from metallic particle suspension must be taken into account in the thermal analysis. The present study investigates the scattering effect on the thermal performance of the DASC employing plasmonic nanofluid as a working fluid. In the analysis, the Monte Carlo method is employed to numerically solve the radiative transfer equation considering the volume scattering inside the nanofluid. It is found that the light scattering can improve the collector performance if the scattering coefficient of nanofluid is carefully engineered depending on its value of the absorption coefficient.

关键词： direct absorption solar collector     plasmonic nanofluid     light scattering    

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Lamellar thickness transition of melt-crystallized polybuten-1 tetragonal phase: configurational change in chain folding directions

Motoi YAMASHITA

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 26-32 doi: 10.1007/s11705-009-0002-2

摘要： Lamellar crystal thickness of isotactic polybutene-1 ( -PB1) have been investigated for crystallization in the melt over a wide range of crystallization temperature from 40°C to 90°C by small angle X-ray scattering experiments and density measurements. The crystal thickness demonstrates two linear dependences on inverse supercooling and a transition from one dependence to the other has been observed around = 65°C. Each of the two dependences obeys the nucleation theory in the high and low supercooling ranges, respectively. Chain folding free energy determined from the low supercooling range is larger than that determined from the high supercooling range. Possible mechanisms for the transition are discussed taking account of entropy of chain folding directions.

关键词： isotactic polybutene-1     tetragonal phase     crystal thickness     melt growth     chain folding     small angle X-ray scattering     nucleation theory     end surface free energy    

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Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

《能源前沿（英文）》 2019年 第13卷 第1期   页码 163-171 doi: 10.1007/s11708-018-0554-2

摘要： This paper focuses on the superiority of organic-inorganic hybrid ion-gel electrolytes for lithium-ion batteries (LiBs) over commercial electrolytes, such as 1 M LiPF in 1:1 ethylene carbonate (EC): dimethyl carbonate (DMC) {1 M LiPF -EC: DMC}, in terms of their flame susceptibility. These ion-gel electrolytes possess ionic liquid monomers, which are confined within the borosilicate or silicate matrices that are ideal for non-flammability. Naked flame tests confirm that the organic-inorganic hybrid electrolytes are less susceptible to flames, and these electrolytes do not suffer from a major loss in terms of weight. In addition, the hybrids are self-extinguishable. Therefore, these hybrids are only oxidized when subjected to a flame unlike other commercial electrolytes used in lithium-ion batteries. Supplementary analyses using differential scanning calorimetric studies reveal that the hybrids are glassy until the temperature reaches more than 100°C. The current results are consistent with previously published data on the organic-inorganic hybrids.

关键词： inorganic polymeric borosilicate network     organic-inorganic hybrids     self-extinguishability     nonflammability     lithium batteries     flame-retardants    

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Solar photovoltaic fed dual input LED lighting system with constant illumination control

Kinattingal SUNDARESWARAN,Kevin Ark KUMAR,Payyalore Raman VENKATESWARAN,Sankaran PALANI

《能源前沿（英文）》 2016年 第10卷 第4期   页码 473-478 doi: 10.1007/s11708-016-0420-z

摘要： A dual input LED lighting scheme with constant illumination is proposed in this paper. The scheme employs a photovoltaic array as the first input and a battery as the second one. A microcontroller is programmed to operate a changeover switch as well as a DC-DC converter for uninterrupted and constant illumination in work place. The scheme is suitable for conference halls, laboratories, clean rooms, marriage halls, theaters, etc. The complete modeling, design and experimentation of the proposed scheme are explained and the economic viability of the scheme is justified.

关键词： photovoltaic     LED light     dual input     P&O algorithm    

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火灾烟雾颗粒的光学散射特性研究

疏学明,方俊,邵荃,袁宏永

《中国工程科学》 2005年 第7卷 第1期   页码 45-49

摘要：

从理论和实验两个方面研究了几种常见的燃烧烟雾在不同波长激光下的散射特性。从Mie散射理论出发，比较几种Mie散射算法的优缺点，采用一种改进的连分式算法对火灾烟雾颗粒的散射光强分布进行计算，得出不同粒径大小和波长下光强分布图。结合理论计算，设计一套实验装置，测量并计算在不同角度下3种烟雾颗粒和面粉气溶胶散射光的相对光强比，实验测量值与理论计算值吻合较好。研究结果表明不同种类烟雾散射光相对光强比互不相同，火灾烟雾与非烟雾气溶胶差距较大，从而表明散射光相对光强比是区分不同烟雾特定的物性参数，为火灾烟雾探测技术发展提供理论依据。

关键词： 火灾烟雾     Mie散射     算法     相对光强比    

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标题 作者 时间 类型 操作

Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhancedRaman spectroscopy substrate

期刊论文

SERS nanoprobes for bio-application

Han-Wen Cheng,Jin Luo,Chuan-Jian Zhong

期刊论文

V-shaped substrate for surface and volume enhanced Raman spectroscopic analysis of microplastics

期刊论文

超短脉冲激光制造及表面加工微米器件

于泳超, 白石, 王树同, 胡安明

期刊论文

Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

期刊论文

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

期刊论文

Enhanced photocatalytic water splitting with surface defective SrTiO

Junying LIU, Zhidong WEI, Wenfeng SHANGGUAN

期刊论文

Chemical mapping of cement pastes by using confocal Raman spectroscopy

Fengjuan LIU,Zhihui SUN

期刊论文

Enhanced production of laccase by

Wei SUN, Meiying XU, Chunyu XIA, Anhua LI, Guoping SUN

期刊论文

Construction of nitrogen-doped carbon cladding LiMnO film electrode with enhanced stability for electrochemically

期刊论文

Effect of light scattering on the performance of a direct absorption solar collector

Kwang Hyun WON, Bong Jae LEE

期刊论文

Lamellar thickness transition of melt-crystallized polybuten-1 tetragonal phase: configurational change in chain folding directions

Motoi YAMASHITA

期刊论文

Flame-retardant properties of

Kumar Sai SMARAN, Rajashekar BADAM, Raman VEDARAJAN, Noriyoshi MATSUMI

期刊论文

Solar photovoltaic fed dual input LED lighting system with constant illumination control

Kinattingal SUNDARESWARAN,Kevin Ark KUMAR,Payyalore Raman VENKATESWARAN,Sankaran PALANI

期刊论文

火灾烟雾颗粒的光学散射特性研究

疏学明,方俊,邵荃,袁宏永

期刊论文